As one of emerging novel surface treatment techniques, laser polishing offers a cost-effective and efficient solution to reduce surface roughness of precision components at micro-/mesoscale. Although it has been applied for industrial and biomedical purposes, the underlying mechanism has not been fully revealed. This paper presents a study to understand the basic fundamentals of continuous wave fiber laser polishing of Ti6Al4V samples. A two-dimensional numerical model that coupled heat transfer and fluid flow is developed to illustrate the molten flow behavior. The roles of capillary and thermocapillary flow in the process of laser polishing are investigated to assist the understanding of the contributions of surface tension (capillary force) and Marangoni effect (thermocapillary force) in the polishing process. Capillary force dominates the molten pool at the initial stage of melting, while thermocapillary force becomes predominant when the molten pool fully develops.